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Typical Properties of Common Rubber Compounds
Physical Properties: What you can't see can definitely hurt
you...
The following table gives general information regarding common rubber
genres and is intended to aid in material selection and design of rubber
parts and products. Rubber compounding is a very broad and
technical field, as basic elastomers are typically mixed with various
chemicals and ingredients (and even with each other) to obtain desired
physical properties and control costs. (Yes, like everyone else,
rubber manufacturers are constantly seeking ways to cut their costs,
including cheapening their products.)
Most commercial rubber products are made to proprietary formulas held
in confidence by the companies producing them. There are, therefore,
literally infinite possible formulations within each genre of rubber
listed below...and (consumer beware) THEY ARE NOT ALL EQUAL!
A wide range of variations on physical properties like tensile strength,
elongation percentage, and abrasion resistance can be found amongst
different commercial rubber products made of the same basic elastomer --
and these are all factors that usually greatly affect the quality and
durability of rubber seals, cushions, and other rubber products.
Other factors like chemical resistance and temperature range also vary,
but normally to a lesser degree, which makes the following information
useful for the purpose of pointing in the right general direction as far
as a rubber compound is concerned.
Dealers of rubber products will generally be happy to accommodate
requests as generic as 'Neoprene', 'Silicone', or any other class of
rubber, but that doesn't necessarily serve the consumer's interest.
At least some of the features listed above and/or others are usually
directly relative to the overall performance and cost of a rubber product,
especially regarding the longevity of its elastomeric properties. In
general, cheaper grades of rubber carry less resistance to elements and
stresses that breakdown the molecular structure of rubber, making it stiff
and brittle rather than rubbery. Physical testing can determine how
well a rubber seal or gasket, for instance, works in a given application,
but only laboratory tests can reveal the underlying qualities that bear
upon how long it will work.
No reputable rubber compounder would mix, mold, extrude, or calender
rubber without testing its physical properties, and consumers should know
that this information bears directly on the true value of the materials
they offer. For various, mostly benign reasons, physical properties
are often only available on request, but they should be readily
available from any reputable dealer of rubber products.
In many cases it is well worth a few pennies more to get a rubber
gasket or seal that is more likely to perform better for longer, but it is
always worth while to know what your buying. If you wouldn't buy
a tire without knowing its mileage rating, don't buy rubber products
without comparing physical properties.
Typical Properties of Common Elastomers (Rubber
Compounds)
Common Name(s)5 |
Designation2 |
Composition |
General Properties1 |
General Chemical
Resistance3 |
Resistent to: |
Attacked by: |
Neoprene |
CR |
Chloroprene |
Good Weathering Resistance.
Flame retarding. Moderate resistance to pertroleum-based
fluids. |
Moderate chemicals and acids,
ozone, oils, fats, greases, many oils, and solvents. |
Strong oxidizing acids, esters,
ketones, chlorinated, aromatic and nitro hydrocarbons. |
EPDM |
EPDM, EPM |
Ethylene-propylene- diene;
Ethylene-propylene |
Excellent ozone, chemical, and
aging resistance. Poor resistance to pertoleum-based
fluids. |
Animal and vegetable oils, ozone,
strong and oxidizing chemicals. |
Mineral oils and solvents,
aromatic hydrocarbons. |
Buna-N |
NBR |
Nitrile-butadiene |
Excellent resistance to
pertoleum-based fluids. Good physical properties. |
Many hydrocarbons, fats, oils,
greases, hydraulic fluids, chemicals. |
Ozone (except PVC blends),
ketones, esters, aldehydes, chlorinated and nitro
hydrocarbons. |
Silicone |
Q, Si |
Polysiloxane |
Excellent high and low temperature
properties. Fair physical properties. |
Moderate or oxidizing chemicals,
ozone, concentrated sodium hydroxide. |
Many solvents, oils, concentrated
acids, dilute sodium hydroxide. |
SBR |
SBR |
Styrene-butadiene |
Good physical properties and
abrasion resistance. Poor resistance to petroleum-based
fluids. |
Most moderate chemicals, wet or
dry, organic acids, alcohols, ketones, aldehydes. |
Ozone, strong acids, fats, oils,
greases, most hydrocarbons. |
Butyl |
IIR |
Isobutene-isoprene |
Very good weathering
resistance. Excellent dialectric properties. Low
permeability to air. Good physical properties. Poor
resistance to petroleum-based fluids. |
Animal and vegetable fats, oils,
greases, ozone, strong and oxidizing chemicals. |
Petroleum, solvents, coal tar
solvents, aromatic hydrocarbons. |
Natural, Gum
Rubber |
NR |
Isoprene, natural |
Excellent physical properties
including abrasion and low temperature resistance. Poor
resistance to petroleum-based fluids. |
Most moderate chemicals, wet or
dry, organic acids, alcohols, ketones, aldehydes. |
Ozone, strong acids, fats, oils,
greases, most hydrocarbons. |
Isoprene, Polyisoprene |
IR |
Isoprene, synthetic |
Similar to natural
rubber. |
Similar to natural
rubber. |
Similar to natural
rubber. |
Hypalon |
CSM |
Chloro-sulfonyl-
polyethylene |
Excellent ozone, weathering, and
acid resistance. Good and abrasion and heat resistance.
Fair resistance to petroleum-based fluids. |
Similar to Neoprene with improved
acid resistance. |
Concentrated oxidizing acids,
esters, ketones, chlorinated, aromatic, and nitro
hydrocarbons. |
Acrylic, Poly Acrylate |
ABR, ACM |
Acrylate-butadiene, copolymer of
acrylic ester and acrylic halide |
Excellent resistance to high
temperature, oil and air, ozone, and weathering. Poor low
temperature properties. Not recommended for water
service. |
Ozone, extreme pressure,
lubricants, hot oils, petroleum solvents, animal and vegetable
fats. |
Water, alcohols, glycols, alkali,
esters, aromatic and halogenated hydrocarbons, phenol. |
Urethane |
AU, EU |
Polyethylene-apdate, Poly (oxy-1,
4, butylene) ether |
Good aging and excellent abrasion,
tear, and solvent resistance. Poor high temperature
properties. |
Ozone, hydrocarbons, moderate
chemicals, fats, oils, greases. |
Concentrated acids, ketones,
esters, chlorinated and nitro hydrocarbons. |
Chlorinated-
polyethylene |
CPE |
Chlorinated-
polyethylene |
Excellent ozone and weathering
resistance; good heat resistance. Moderate resistance to
petroleum-based fluids. |
|
|
Viton4,
Fluoro-elastomer |
FPM |
Hexaflouropropylene- vinylidene
flouride |
Excellent oil and air resistance
both at low and high temperatures. Very good chemical
resistance. |
All aliphatic, aromatic and
halogenated hydrocarbons, acids, animal and vegetable
oils. |
Ketones, low molecular weight
esters and nitro containing compounds. |
Butadiene
rubber |
BR |
Polybutadiene |
Excellent abrasion resistance and
low temperature properties. High resilience. |
Similar to SBR |
Similar to
SBR |
Kalrez4 |
AFMU |
Tetraflouroethylene- flouronitrosomethane-
perflourobutyric acid |
Excellent chemical
resistance. Excellent high and low temperature
properties. |
|
|
Hydrin,
Herchlor |
CO |
Polychloromethyl
oxirane |
Excellent oil and ozone
resistance. Good flame resistance and low permeability to
gases. Fair low temperature properties. |
Similar to nitrile with ozone
resistance. |
Ketones, esters,
aldehydes, chlorinated and nitro hydrocarbons. |
ECH, Hydrin,
Herchlor |
ECO |
Ethylene oxide
and chloromethyl oxirane |
Good low temperature
properties. Excellent oil and ozone resistance. Fair
flame resistance. Low permeability to gases. |
Similar to nitrile with ozone
resistance. |
Ketones, esters,
aldehydes, chlorinated and nitro hydrocarbons. |
Fluoro-silicone |
FSi |
Flourocarbon |
|
Moderate or oxidizing chemicals,
ozone, aromatic chlorinated solvents, bases. |
Brake fluids,
hydrazine, ketones. |
Standard Gasket and Rubber Products carries a wide variety
of rubber products for an even broader array of applications.
Rubber hardnesses commonly range from 30 to 90 durometer (Shore A) and are
available in many standard, semi-standard, and custom compounds to cover
virtually any requirement. SG carries a large inventory containing some
styles of most of the classes of elastomers listed above.
Related Pages
Resources, Links, Technical Information
Footnotes
- From the "Sheet Rubber Handbook - Gasket and Packing
Materials" publication #IP-40 of the Rubber Manufacturers Association
(RMA).
- ASTM D 1418-79
- 1979 Yearbook of the Los Angeles Rubber Group, Inc.
- "Viton" and "Kalrez" are registered trademarks of
E.I. Dupont, Inc.
- Boldface indicates standard material.
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